Nonlinear Optical Studies of Interfaces

49. Topological properties of interfacial hydrogen bond networks
Ruiyu Wang, Mark DelloStritto, Michael L. Klein, Eric Borguet, and Vincenzo Carnevale
Physical Review B 110, 014105 (2024)

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48. Bridging Molecular-Scale Interfacial Science with Continuum-Scale Models
Anastasia Ilgen, Eric Borguet, Franz Geiger, Julianne Gibbs, Vicki Grassian, Young-Shin Jun, Nadine Kabengi, and James Kubicki
Nature Communications (15), 5326 (2024)
DOI: 10.1038/s41467-024-49598-y

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47. The influence of charged site density on local electric fields and polar solvent organization at oxide interfaces
Somaiyeh Dadashi, Shyam Parshotam, Bijoya Mandal, Benjamin Rehl, Julianne Gibbs, and Eric Borguet
Journal of Physical Chemistry C 128 (23), 9683–9692 (2024)
DOI:10.1021/acs.jpcc.4c00306

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46. Cation Modifies Interfacial Water Structures on Platinum during Alkaline Hydrogen Electrocatalysis
Pengtao Xu, Ruiyu Wang, Haojian Zhang, Vincenzo Carnevale, Eric Borguet, and Jin Suntivich
Journal of the American Chemical Society 146 (4), 2426–2434 (2024).
DOI: 10.1021/jacs.3c09128

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45. Vibrational Spectroscopy of Geochemical Interfaces
Stefan M. Piontek and Eric Borguet
Surface Science Reports 78 (4), 100606 (2023)

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44. Oxide- and Silicate-Water Interfaces and Their Roles in Technology and the Environment
Jose Banuelos, Eric Borguet, Gordon Brown, Randall Cygan, James De Yoreo, Patricia Dove, Marie-Pierre Gaigeot, Franz Geiger, Julianne Gibbs, Vicki Grassian, Anastasia Ilgen, Young-shin Jun, Nadine Kabengi, Lynn Katz, James Kubicki, Johannes Lutzenkirchen, Christine Putnis, Richard Remsing, Kevin Rosso, Gernot Rother, Marialore Sulpizi, Mario Villalobos, Huichun Zhang

Chemical Reviews 123 (10), 6413–6544 (2023)
DOI: 10.1021/acs.chemrev.2c00130 

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43. Superhydrophilicity of α-Alumina Surfaces Results from Tight Binding of Interfacial Waters to Specific Aluminols
Ruiyu Wang, Yunqian Zou, Richard C. Remsing, Naomi O. Ross, Michael L. Klein, Vincenzo Carnevale, and Eric Borguet
Journal of Colloid & Interface Science 628, Part A, 943-954 (2022)

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42. Vibrational Dynamics at Aqueous-Mineral Interfaces
Stefan M. Piontek and Eric Borguet
The Journal of Physical Chemistry C 126(5), 2307–2324 (2022)

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41. Investigation of Water/Oxide Interfaces by Molecular Dynamics Simulations
Ruiyu Wang, Michael Klein, Vincenzo Carnevale, and Eric Borguet,
WIREs Computational Molecular Science 11(6), e1537 (2021)

40. Probing Heterogeneous Charge Distributions at the α-Al2O3(0001)/H2O Interface
Stefan M. Piontek, Mark DelloStritto, Bijoya Mandal, Tim Marshall, Michael L. Klein, and Eric Borguet
Journal of the American Chemical Society 142 (28), 12096–12105 (2020)
DOI: 10.1021/jacs.0c01366                                                                                                                                                                                         Supporting Information

 

39. Ions Induce Order in the Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces
Aashish Tuladhar, Shalaka Dewan, Simone Pezzotti, Flavio Siro Brigiano, Fabrizio Creazzo, Marie-Pierre Gaigeot, and Eric Borguet
Journal of the American Chemical Society 142(15), 6991-7000 (2020)
DOI: 10.1021/jacs.9b13273                                                                                                                                                                                           Supporting Information

38. First Principles Calculation of Water pKa using the Newly Developed SCAN Functional
Ruiyu Wang, Vincenzo Carnevale, Michael Klein and Eric Borguet
The Journal of Physical Chemistry Letters 11 (1), 54-59, (2020)
DOI: 10.1021/acs.jpclett.9b02913                                                                                                                                                                                    Supporting Information

37. Monovalent and Divalent Cations at the α-Al2O3(0001)/Water Interface: How Cation Identity Affects Interfacial Ordering and Vibrational Dynamics
Stefan Piontek, Aashish Tuladhar, Tim Marshall, Eric Borguet
The Journal of Physical Chemistry C 123(30), 18315-18324 (2019)
DOI: 10.1021/acs.jpcc.9b01618                                                                                                                                                                                Supporting Information

36. Sodium Halide Adsorption and Water Structure at the α-Alumina(0001)/Water Interface 
Ruiyu Wang, Mark DelloStritto, Richard Remsing, Vincenzo Carnevale, Michael Klein, Eric Borguet
The Journal of Physical Chemistry C (123), 15618-15628 (2019)
DOI: 10.1021/acs.jpclett.9b00016                                                                                                                                                                                 Supporting Information

35. Bond-Dependent Thole Model for Polarizability and Spectroscopy 
Mark DelloStritto, Michael Klein and Eric Borguet
The Journal of Physical Chemistry A 123 (25), 5378-5387 (2019)
DOI: 10.1021/acs.jpca.8b12011                                                                                                                                                                                 Supporting Information

34. Effect of Functional and Electron Correlation on the Structure and Spectroscopy of the Al2O3(001)-H2O Interface 
Mark DelloStritto, Stefan M. Piontek, Michael Klein and Eric Borguet.
Journal of Physical Chemistry Letters (10), 2031-2036 (2019)
DOI: 10.1021/acs.jpclett.9b00016                                                                                                                                                                                    Supporting Information

33. Relating Interfacial Order to Sum Frequency Generation with Ab Initio Simulations of the Aqueous Al2O3(0001) and (112Ì…0) Interfaces
Mark DelloStritto, Stefan M. Piontek, Michael L. Klein, and Eric Borguet.
The Journal of Physical Chemistry C 122 (37), 21284-21294 (2018)
DOI: 10.1021/acs.jpcc.8b02809                                                                                                                                                                                        Supporting Information

32. The Effect of Halide Ions on the Structure and Dynamics of Water Next to an Alumina (0001) Surface
Aashish Tuladhar, Stefan M. Piontek, Laszlo Frazer, and Eric Borguet.
The Journal of Physical Chemistry C 122 (24), 12819-12830 (2018)
DOI: 10.1021/acs.jpcc.8b03004                                                                                                                                                                                     Supporting Information

31. Insights on Interfacial Structure, Dynamics and Proton Transfer from Ultrafast
Vibrational Sum Frequency Generation Spectroscopy of the Alumina(0001)/Water Interface

Aashish Tuladhar, Stefan Piontek, and Eric Borguet.
The Journal of Physical Chemistry C 121 (9), 5168-5177 (2017)
DOI: 10.1021/acs.jpcc.7b00499                                                                                                                                                                                     Supporting Information

30. Capturing the Ultrafast Vibrational Decoherence of Hydrogen Bonding in Interfacial Water
Abdelaziz Boulesbaa and Eric Borguet
The Journal of Physical Chemistry Letters (7), 5080-5085 (2016)
DOI: 0.1021/acs.jpclett.6b01870                                                                                                                                                                                       Supporting Information

29. Spectroscopy and Ultrafast Vibrational Dynamics of Strongly Hydrogen Bonded OH Species at the α-Al2O3(11-20)/H2O Interface
Aashish Tuladhar, Shalaka Dewan, James Kubicki, and Eric Borguet.
The Journal of Physical Chemistry C 120 (29), 16153-16161, (2016).
DOI: 10.1021/acs.jpcc.5b12486                                                                                                                                                                                        Supporting Information

28. The Structure of Water at Charged Interfaces: A Molecular Dynamics Study
Shalaka Dewan, Vincenzo Carnevale, Arindam Bankura, Ali Eftekhari-Bafrooei, Giacomo Fiorin, Michael Klein, and Eric Borguet
Langmuir 30 (27), 8056-8065 (2014). 
DOI: 10.1021/la5011055  

27. Vibrational Dynamics of Interfacial Water by Free Induction Decay Sum-Frequency Generation (FID-SFG) at the Al2O3(1120)/H2O Interface
Abdelaziz Boulesbaa, and Eric Borguet
The Journal of Physical Chemistry Letters (5), 528-533 (2014).
DOI: 10.1021/jz401961j                                                                                                                                                                                          Supporting Information

26. Hydrophobicity of hydroxylated amorphous fused silica surfaces
Oleksandr Isaienko and Eric Borguet
Langmuir 29 (25), 7885-7895 (2013)
DOI: 10.1021/la401259r  

25. Experimental Correlation between Interfacial Water Structure and Mineral Reactivity
Shalaka Dewan, Mohsen Yeganeh, and Eric Borguet
The Journal of Physical Chemistry Letters (4), 1977-1982 (2013)
DOI: 10.1021/jz4007417                                                                                                                                                                                         Supporting Information

24. Observation of the Bending Mode of Interfacial Water at Silica Surfaces by Near Infrared Vibrational Sum-Frequency Generation Spectroscopy of the [stretch+bend] Combination Bands.
Oleksandr Isaienko, Satoshi Nihonyanagi, Devika Sil, and Eric Borguet
The Journal of Physical Chemistry Letters (4), 531-535, (2013)
DOI: 10.1021/jz3015088                                                                                                                                                                                       Supporting Information

23. Spectroscopy and Dynamics of the Multiple Free OH Species at an Aqueous/Hydrophobic Interface 
Ali Eftekhari-Bafrooei, Satoshi Nihonyanagi, and Eric Borguet
The Journal of Physical Chemistry C 116 (41), 21734-21741 (2012)
DOI: 10.1021/jp210090h 

22. Ultra-broadband high signal-to-noise sum-frequency spectrometer of aqueous interfaces based on a non-collinear optical parametric amplifier.
Oleksandr Isaienko and Eric Borguet
Optics Express 20 (1), 547-561 (2012)
DOI: 10.1364/OE.20.000547  

21. The Effect of Electric Fields on the Ultrafast Vibrational Relaxation of Water at a Charged Solid-Liquid Interface as Probed by Vibrational Sum Frequency Generation
A. Eftekhari-Bafrooei and Eric Borguet
The Journal of Physical Chemistry Letters (2), 1353-1358 (2011).
DOI: 10.1021/jz200194e  1                                                                                                                                                                                      Supporting Information

20. Ultrafast vibrational dynamics and spectroscopy of a siloxane self-assembled monolayer
Satoshi Nihonyanagi, Ali Eftekhari-Bafrooei, and Eric Borguet
The Journal of Chemical Physics (134), 084701 (2011).
DOI: 10.1063/1.3518457  1

19. Second Harmonic Generation Probing of Dopant Type and Density at the Si/SiO2 Interface
J.L. Fiore, V. Fomenko, D. Bodlaki and Eric Borguet
Applied Physics Letters (98), 041905 (2011).
DOI: 10.1063/1.3505356 

18. Linking Surface Potential and Deprotonation in Nanoporous Silica: second harmonic generation and acid/base titration
R. Kramer Campen, Allison K. Pymer, Satoshi Nihonyanagi and Eric Borguet
Journal of Physical Chemistry C 114 (43), 18465-18473 (2010).
DOI: 10.1021/jp1037574            

17. Effect of hydrogen bond strength on the vibrational relaxation of interfacial water
Ali Eftekhari-Bafrooei and Eric Borguet
Journal of the American Chemical Society 132 (11), 3756-3761 (2010).
DOI: 10.1021/ja907745r 

16. Neuronal adhesion and differentiation driven by nanoscale surface free-energy gradients
Guillaume Lamour, Ali Eftekhari-Bafrooei, Eric Borguet, Sylvie Soues, and Ahmed Hamraoui
Biomaterials 31(14), 3762-3771 (2010).
DOI: 10.1016/j.biomaterials.2010.01.09 9  

15. Effect of Surface Charge on the Vibrational Dynamics of Interfacial Water
Ali Eftekhari-Bafrooei and Eric Borguet
Journal of the American Chemical Society 131 (34), 12034-12035 (2009).
DOI: 10.1021/ja903340e  

14. Second Harmonic Generation as a Probe of Multisite Adsorption at Solid Liquid Interfaces of Aqueous Colloid Suspensions
R. Kramer Campen, De-sheng Zheng, Hongfei Wang, and Eric Borguet
Journal of Physical Chemistry C 111 (25), 8805-8813 (2007).
DOI: 10.1021/jp061730h           

13. Photoreactivity of Si(111)-H in Ambient 
Dora Bodlaki and Eric Borguet
Journal of Physical Chemistry C 111(1), 234-239 (2007).
DOI: 10.1021/jp0639546         

12. Ultrafast Hot Carrier Dynamics at Chemically Modified Ge Interfaces Probed by SHG 
Arthur McClelland, Vasiliy Fomenko, and Eric Borguet
Journal of Physical Chemistry B 110 (40), 19784 -19787 (2006).
DOI: 10.1021/jp0460700
           

11. Optical Second Harmonic Generation Studies of Ultrathin High-K Dielectric Stacks
Vasiliy Fomenko, E.P. Gusev, nd Eric Borguet
Journal of Applied Physics 97 (8), 83711, (2005).
DOI: 10.1063/1.1861146

10. Ultrafast time-evolution of the Nonlinear Susceptibility of Hot Carriers at the Ge(111)-GeO2 Interface as Probed by SHG
Arthur McClelland, Vasiliy Fomenko, and Eric Borguet
Journal of Physical Chemistry B 108 (12), 3789-3793 (2004).
DOI: 10.1021/jp036231k           

9. In situ Second Harmonic Generation Measurements of the Stability of Si(111)-H and Kinetics of Oxide Regrowth in Ambient
Dora Bodlaki and Eric Borguet
Journal of Applied Physics 95 (9), 4675-4680 (2004).
DOI: 10.1063/1.1664024  

8. Dynamics and Second Order Nonlinear Optical Susceptibility of Photo Excited Carriers at Si(111) Interfaces
Dora Bodlaki and Eric Borguet
Applied Physics Letters (83), 2357-2359 (2003).
DOI: 10.1063/1.1592893  

7. Combined Electron-Hole Dynamics at UV-Irradiated Si-SiO2 Interfaces Probed by Second Harmonic Generation 
Vasiliy Fomenko and Eric Borguet
Physical Review B (68), 081301(R) (2003).
DOI: 10.1103/PhysRevB.68.081301   

6. Infrared Second Harmonic Generation Spectroscopy of Germanium Interfaces
Dora Bodlaki, E. Freysz, and Eric Borguet
Journal of Chemical Physics (119), 3958-3962 (2003).
DOI: 10.1063/1.1578619  

5. Ambient Stability of Chemically Passivated Germanium Interfaces
Dora Bodlaki, H. Yamamoto, David H. Waldeck, and Eric Borguet
Surface Science (543), 63-74 (2003).
DOI: 10.1016/S0039-6028(03)00958-0   

4. Second Harmonic Generation from Chemically Modified Ge(111) Interfaces
Vasiliy Fomenko, Dora Bodlaki, Catherine Faler, and Eric Borguet
Journal of Chemical Physics (116), 6745-6754 (2002).
DOI: 10.1063/1.1454242 

3. Second Harmonic Generation Investigations of Charge Transfer at Chemically Modified Semiconductor Interfaces
Vasiliy Fomenko, Cedric Hurth, Tao Ye, and Eric Borguet
Journal of Applied Physics (91), 4394-4398 (2002).
DOI: 10.1063/1.1452774   

2. Non-Quadratic Second Harmonic Generation from Semiconductor-Oxide Interfaces
Vasiliy Fomenko, Jean-Frédéric Lami, and Eric Borguet
Physical Review B (63), 121316 (2001).
DOI: 10.1103/PhysRevB.63.121316   

1. Picosecond Infrared Optical Parametric Amplifier for Nonlinear Interface Spectroscopy
Dora Bodlaki and Eric Borguet
Review of Scientific Instruments (71), 4050-4056 (2000).
DOI: 10.1063/1.1321302