Nonlinear Optical Studies of Solid-Liquid Interfaces

28. 

Investigation of Water/Oxide Interfaces by Molecular Dynamics Simulations
 Ruiyu Wang, Michael Klein, Vincenzo Carnevale, and Eric Borguet, WIREs Computational
WIREs Comput Mol. Sci, e1537 (2021)

27. Probing Heterogeneous Charge Distributions at the α-Al2O3(0001)/H2O Interface
Stefan M. Piontek, Mark DelloStritto, Bijoya Mandal, Tim Marshall, Michael L. Klein, and Eric Borguet
J. Am. Chem. Soc., 142, 28, 12096–12105 (2020)
DOI:10.1021/jacs.0c01366                                                                                                                                                                                      Supporting Information

26. Ions Induce Order in the Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces
Aashish Tuladhar, Shalaka Dewan, Simone Pezzotti, Flavio Siro Brigiano, Fabrizio Creazzo, Marie-Pierre Gaigeot, and Eric Borguet
Journal of the American Chemical Society 142(15) 6991-7000 (2020)
DOI: 10.1021/jacs.9b13273                                                                                                                                                                                           Supporting Information

25. First Principles Calculation of Water pKa using the Newly Developed SCAN Functional
Ruiyu Wang, Vincenzo Carnevale, Michael Klein and Eric Borguet
The Journal of Physical Chemistry Letters 11, 1, 54-59, (2020)
DOI: 10.1021/acs.jpclett.9b02913                                                                                                                                                                                    Supporting Information

24. Monovalent and Divalent Cations at the α-Al2O3(0001)/Water Interface: How Cation Identity Affects Interfacial Ordering and Vibrational Dynamics
Stefan Piontek, Aashish Tuladhar, Tim Marshall, Eric Borguet
The Journal of Physical Chemistry C, 123(30), 18315-18324 (2019)
DOI:10.1021/acs.jpcc.9b01618                                                                                                                                                                               Supporting Information

23. Sodium Halide Adsorption and Water Structure at the α-Alumina(0001)/Water Interface 
Ruiyu Wang, Mark DelloStritto, Richard Remsing, Vincenzo Carnevale, Michael Klein, Eric Borguet
The Journal of Physical Chemistry C, 123, 15618-15628 (2019)
DOI: 10.1021/acs.jpclett.9b00016                                                                                                                                                                               Supporting Information

22. Bond-Dependent Thole Model for Polarizability and Spectroscopy 
Mark DelloStritto, Michael Klein and Eric Borguet
The Journal of Physical Chemistry A, 123, 25, 5378-5387 (2019)
DOI: 10.1021/acs.jpca.8b12011                                                                                                                                                                                  Supporting Information

21. Effect of Functional and Electron Correlation on the Structure and Spectroscopy of the Al2O3(001)-H2O Interface 
Mark DelloStritto, Stefan M. Piontek, Michael Klein and Eric Borguet.
Journal of Physical Chemistry Letters, 10, 2031-2036 (2019)
DOI: 10.1021/acs.jpclett.9b00016                                                                                                                                                                                Supporting Information

20. Relating Interfacial Order to Sum Frequency Generation with Ab Initio Simulations of the Aqueous Al2O3(0001) and (112͞0 ) Interfaces
Mark DelloStritto, Stefan M. Piontek, Michael L. Klein, and Eric Borguet.
The Journal of Physical Chemistry C, 122 (37), 21284-21294 (2018)
DOI: 10.1021/acs.jpcc.8b02809                                                                                                                                                                               Supporting Information

19. The Effect of Halide Ions on the Structure and Dynamics of Water Next to an Alumina (0001) Surface
Aashish Tuladhar, Stefan M. Piontek, Laszlo Frazer, and Eric Borguet.
The Journal of Physical Chemistry C, 122 (24), 12819-12830 (2018)
DOI: 10.1021/acs.jpcc.8b03004                                                                                                                                                                                Supporting Information

18. Insights on Interfacial Structure, Dynamics and Proton Transfer from Ultrafast
Vibrational Sum Frequency Generation Spectroscopy of the Alumina(0001)/Water Interface

Aashish Tuladhar, Stefan Piontek, and Eric Borguet.
The Journal of Physical Chemistry C, 121 (9), 5168-5177 (2017)
DOI: 10.1021/acs.jpcc.7b00499                                                                                                                                                                              Supporting Information

17. Capturing the Ultrafast Vibrational Decoherence of Hydrogen Bonding in Interfacial Water
Abdelaziz Boulesbaa and Eric Borguet
The Journal of Physical Chemistry Letters 7, 5080-5085 (2016)
DOI: 0.1021/acs.jpclett.6b01870                                                                                                                                                                               Supporting Information

16. Spectroscopy and Ultrafast Vibrational Dynamics of Strongly Hydrogen Bonded OH Species at the α-Al2O3(11-20)/H2O Interface
Aashish Tuladhar, Shalaka Dewan, James Kubicki, and Eric Borguet.
The Journal of Physical Chemistry Letters 120 (29), 16153-16161, (2016)
DOI: 10.1021/acs.jpcc.5b12486                                                                                                                                                                                Supporting Information

15. The Structure of Water at Charged Interfaces: A Molecular Dynamics Study
Shalaka Dewan, Vincenzo Carnevale, Arindam Bankura, Ali Eftekhari-Bafrooei, Giacomo Fiorin, Michael Klein, and Eric Borguet
Langmuir 30 (27), 8056-8065 (2014). 
DOI: 10.1021/la5011055  

14. Vibrational Dynamics of Interfacial Water by Free Induction Decay Sum-Frequency Generation (FID-SFG) at the Al2O3(1120)/H2O Interface
Abdelaziz Boulesbaa and Eric Borguet
The Journal of Physical Chemistry Letters, 5, 528-533 (2014)
DOI:10.1021/jz401961j                                                                                                                                                                                Supporting Information

13. Generation of Sub-30-fs Microjoule Mid-infrared Pulses for Ultrafast Vibrational Dynamics at Solid/Liquid Interfaces
Abdelaziz Boulesbaa. Oleksandr Isaienko, Aashish Tuladhar, and Eric Borguet
Optics Letters, 38 (23), 5008-5011 (2013).
DOI: 10.1364/OL.38.00500  

12. Hydrophobicity of hydroxylated amorphous fused silica surfaces
Oleksandr Isaienko and Eric Borguet
Langmuir, 29 (25), 7885-7895 (2013).
DOI: 10.1021/la401259r  

11. Experimental Correlation between Interfacial Water Structure and Mineral Reactivity
Shalaka Dewan, Mohsen Yeganeh, and Eric Borguet
The Journal of Physical Chemistry Letters 4, 1977-1982 (2013).
DOI:10.1021/jz4007417                                                                                                                                                                                 Supporting Information

10. Observation of the Bending Mode of Interfacial Water at Silica Surfaces by Near Infrared Vibrational Sum-Frequency Generation Spectroscopy of the [stretch+bend] Combination Bands.
Oleksandr Isaienko, Satoshi Nihonyanagi, Devika Sil, and Eric Borguet
The Journal of Physical Chemistry Letters 4, 531-535, (2013).
DOI:10.1021/jz3015088                                                                                                                                                                                                      Supporting Information

9. Spectroscopy and Dynamics of the Multiple Free OH Species at an Aqueous/Hydrophobic Interface 
Ali Eftekhari-Bafrooei, Satoshi Nihonyanagi, and Eric Borguet
The Journal of Physical Chemistry C 116 (41), 21734-21741 (2012).
DOI:10.1021/jp210090h 

8. Ultra-broadband high signal-to-noise sum-frequency spectrometer of aqueous interfaces based on a non-collinear optical parametric amplifier.
Oleksandr Isaienko and Eric Borguet
Optics Express, 20 (1), 547-561 (2012).
DOI:10.1364/OE.20.000547  

7. The Effect of Electric Fields on the Ultrafast Vibrational Relaxation of Water at a Charged Solid-Liquid Interface as Probed by Vibrational Sum Frequency Generation
A. Eftekhari-Bafrooei and Eric Borguet
Journal of Physical Chemistry Letters 2, 1353-1358 (2011).
DOI:10.1021/jz200194e  1                                                                                                                                                                              Supporting Information

6. Ultrafast vibrational dynamics and spectroscopy of a siloxane self-assembled monolayer
Satoshi Nihonyanagi, Ali Eftekhari-Bafrooei, and Eric Borguet
The Journal of Chemical Physics 134, 084701 (2011).
DOI: 10.1063/1.3518457  1

5. Linking Surface Potential and Deprotonation in Nanoporous Silica: second harmonic generation and acid/base titration
R. Kramer Campen, Allison K. Pymer, Satoshi Nihonyanagi, and Eric Borguet
Journal of Physical Chemistry C 114 (43), 18465-18473 (2010).
DOI: 10.1021/jp1037574  

4. Effect of hydrogen bond strength on the vibrational relaxation of interfacial water
Ali Eftekhari-Bafrooei and Eric Borguet
Journal of the American Chemical Society 132 (11), 3756-3761 (2010).
DOI: 10.1021/ja907745r 

3. Neuronal adhesion and differentiation driven by nanoscale surface free-energy gradients
Guillaume Lamour, Ali Eftekhari-Bafrooei, Eric Borguet, Sylvie Soues, and Ahmed Hamraoui
Biomaterials 31(14), 3762-3771 (2010).
DOI: 10.1016/j.biomaterials.2010.01.099  

2. Effect of Surface Charge on the Vibrational Dynamics of Interfacial Water
Ali Eftekhari-Bafrooei and Eric Borguet
Journal of the American Chemical Society 131 (34), 12034-12035 (2009).
DOI: 10.1021/ja903340e                                                                                                                                                                               Supporting Information

1. Second Harmonic Generation as a Probe of Multi-site Adsorption at Solid Liquid Interfaces of Aqueous Colloid Suspensions
R. Kramer Campen, De-sheng Zheng, Hongfei Wang, and Eric Borguet
Journal of Physical Chemistry C, 111 (25), 8805-8813 (2007).
DOI: 10.1021/jp061730h